All Atoms and bonds articles – Page 23
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ResearchAlgorithm increases certainty of stereochemical assignments in flexible molecules
Computational fitting procedure set to reinvigorate vibrational circular dichroism spectroscopy
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OpinionFluorine: the T rex of the periodic table
Pass out the nickel superalloy reactor kit, it’s time to tame that most reactive of elements
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FeaturePlutonium: The element factory
Glenn Seaborg’s lab at Berkeley discovered plutonium – an element with uses beyond the deadly one we know well
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ResearchUncertainty metric builds confidence in machine learned-chemistry
Calculation will help users recognise when they need to retrain a neural network
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OpinionMachine-learning Mendeleevs have rediscovered the periodic table
Exposing new dimensions in the relationships between elements
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![An image showing (P)-M[28]3·ZnLn](https://d2cbg94ubxgsnp.cloudfront.net/Pictures/100x67/4/7/5/144475_ja-2019-04074d_0005.jpg)
ResearchMolecular amplifier makes purest chiral Möbius aromatic
Stack of chiral components creates most enantiopure twisted aromatic ring ever made
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ResearchAFM captures changing structures of charged molecules
Technique that adds electrons one by one could enable new molecules to be synthesised by atomic manipulation
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OpinionThe silent rise of the robots
Mechanical helpers have been creeping into our labs for decades
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OpinionDo you know about C–H‧‧‧O?
The C–H‧‧‧O hydrogen bond controversy has long been resolved – we should tell our students
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FeatureThe forgotten female crystallographer who discovered C–H⋯O bonds
Andy Extance tells the overlooked story of crystallographer June Sutor, whose C–H⋯O bonding hypothesis was unjustly suppressed
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OpinionThe third degree on actinide covalency
The often ignored elements are attracting chemists’ attention again
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ResearchSolubility simulations solve mystery of why PEG dissolves in water but Keck clips don’t
Answer to puzzle of why such similar polyethers behave so differently could lead to better predictions of a molecule’s solubility
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ResearchIonisation energy of promethium fills one of the last holes in periodic table
Experiment puts an end to 75-year-old mystery
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FeatureP is for phosphorus
A reporter from Alchemistry World reveals the unpleasant secret behind The Alchemist Discovering Phosphorus
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ResearchFirst 4D look at crystallising atoms contradicts textbook nucleation theory
Tracking individual atoms over time in a solid-to-solid phase puts another nail in classical nucleation theory’s coffin
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ResearchFloppiness scale untangles knotted molecules
Chemists use floppiness factor to characterise mechanically interlocked molecules using mass spectrometry
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ResearchLaser centrifuge spins out chiral molecules in world first
Experimental proof that molecule’s rotation can be controlled with light could lead to new ways to separate enantiomers
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ResearchFirst isolable thorium nitride complex made
Researchers use new complex to probe covalency of actinide–ligand double bonds
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ResearchChiral borane complexes catalyse new synthesis opportunities
N-heterocyclic carbene-borane complexes with a rare stereogenic boron centre demonstrate potential in stereoselective catalysis