Chemical bonding – Page 3
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ResearchHydrogen bonds join forces to maximise water–water interaction
Cooperative environment encourages stronger chemistry
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ResearchSimulation says supercritical water has no hydrogen bonds
Computational approach seeks to clarify bonding confusion
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ResearchHydrogen bond imparts more stability on transition state than expected
Study reveals importance of repulsive interactions
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ResearchMacrocycles slide freely across carbon nanotubes
Simulations suggest macrocycles show superlubricity at room temperature
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ResearchExcited state potential energy curves reignite diatomic carbon’s bond order conundrum
Molecular orbital theory-based approach backs quadruple bond
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ResearchBeautiful molecules ring up with a purpose
How Stephen Goldup used his experience in organic synthesis to find a supramolecular niche
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ResearchNew silicon–silicon bond is a rare example of a π bond without a σ bond
Discovery made in silicon analogue of bicyclobutane
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ResearchHydrogen bonds are single atom nickel’s secret for carbon dioxide reduction
Computational calculations show that hydrogen atoms and charge capacity are behind nickel’s high activity and selectivity in electrochemical carbon dioxide reduction
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ResearchNew type of bond is the first to defy actinide contraction trend
Bonds discovered in metallacycles are unique to the 5f elements
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![An image showing a [2]catenane](https://d2cbg94ubxgsnp.cloudfront.net/Pictures/100x67/0/0/4/504004_fja0c01757_0007.jpeg_49119.jpg)
ResearchMechanical protecting group shields molecules from stress and strain
Catenane makes force-activated molecules more resistant mechanical bond breaking
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![An image showing the bonding pattern of [2]catenane](https://d2cbg94ubxgsnp.cloudfront.net/Pictures/100x67/2/8/7/503287_c9cc09483kf2_286914.png)
ResearchAromaticity lends stability to carbon-only catenanes
Catenanes of newly discovered C18 rings are theoretically possible thanks to the kinetic quirks of aromaticity
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ResearchRhenium plays starring role in bond movie
Controllable energy input from transmission electron microscope captures atoms dissociating and recombining
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ResearchOdd 'entropic bonds' akin to chemical ones can form between nanoparticles
Simulations finds that ’bonding’ can occur in the absence of any electronic interaction
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OpinionWill computers ever discover drugs from scratch?
With enough understanding and computing power, it should be possible, but will it happen?
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ResearchThree centres, two electrons, but how many bonds?
Tweaking Lewis structures allows for a simplified and clearer representation of electron-deficient molecules
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ResearchCarbynes expand the possibilities of carbon–carbon double bonds
Chemists use novel monovalent carbon species to insert functionalities in the middle of double bonds
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ResearchGiant tree molecule made out of 45 rotaxanes switches size on demand
Mechanically interlocked molecules give dendrimer the ability to expand and contract
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ResearchFirst ever synthesis of most double-bond-rich hydrocarbon
Tiny hydrocarbon with six double bonds has unrivalled ability to make complex ring systems though multiple Diels–Alder reactions
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