Inorganic chemistry – Page 13
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ResearchFirst arsenic–germanium double bond made
Scientists use push–pull substitution to synthesise heavy imine
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ResearchCuboctahedral copper cluster promotes main group coordination to new high
First examples of compounds in which a sulfide, chloride or bromide ion holds so large a coordination number
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ResearchAI teaches itself to identify materials – and predict new ones too
Neural network trained up on 50,000 crystal structures shows promise rapidly navigating chemical element combinations
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ResearchLaser spectroscopy offers first glimpse at nobelium nuclei
Adapted technique offers experimental insights to theorists studying superheavy elements
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NewsNoble gas’s days of fixed atomic weight argon
Chemistry’s standardisation body introduces atomic weight interval for argon and updates weights of another 13 elements
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ResearchNew route to +3 oxidation state of neptunium
Tetrahydrofuran steers chemists towards a low-valent neptunium precursor
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ResearchNew rationale for 15-element wide f block
Scientists seek to settle periodic table layout debate
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ResearchTin–cobalt compound used as oligomerisation catalyst
First example of a four-coordinate tin radical made by photolysis of a metal–metal bond
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PodcastIndium tin oxide, ITO
Swipe, tap, pinch, poke and prod – Neil Withers gets hands on with touchscreen material indium tin oxide
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![[Th(III)]–[Al] complex [Cp‡2Th(m-H3)AlC(SiMe3)3 (left) and [Cp‡2U(m-H3)AlC(SiMe3)3 (right)](https://d2cbg94ubxgsnp.cloudfront.net/Pictures/100x67/7/3/7/136737_c8sc01260a-f2.jpg)
ResearchFirst actinide–metal complexes with dative bonds
5f and 6d orbitals in low-valent actinides exhibit unprecedented charge transfer in actinide–metal complexes
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ResearchCopper–arene complex tamed by silylene
Ligand selection unleashes first monomeric [Cu(η6-C6H6)]+ complex
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ResearchUnlimited combinations possible for new range of atom thick materials
Molten salts allow synthesis of 35 unknown 2D transition metal chalcogenides with many more possible
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Research73 new exotic nuclei discovered at Japanese institute
Hunt for remaining 4000 predicted nuclides goes on but new technology is needed to find them all
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ResearchAnionic aluminium turns textbook knowledge on its head
First stable nucleophilic aluminium(I) compound offers new way to make aluminium–carbon bonds
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ResearchHundreds of helium compounds could be hiding in Earth’s mantle
Although it doesn’t form any bonds, the noble gas can form compounds with salts at high pressure
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ResearchTwo atom reaction smallest chemistry experiment ever performed
Exquisite manipulation of a single sodium and caesium atom could herald start of an era of total control over chemistry
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ResearchCoordination trick reinvents cobalt and nickel as carbon reduction catalysts
When it comes to reducing carbon dioxide, being well coordinated is a disadvantage
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ResearchBizarre bimetallic compounds break C–F bonds
First ever molecular Mg–Al bond constructed in study that reveals main group metal–metal bonds can readily react with aromatic fluorine
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ResearchTitanium complex converts methane to alkenes at room temperature
New work illustrates the ‘crucial steps’ required for a process to make useful chemical feedstocks from methane