Inorganic chemistry – Page 14
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ResearchMaterial containing perfectly planar octacoordinate titanium predicted
Titanium falls flat in an eight-membered boron ring
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ResearchElectro-shock treatment switches MOF on to gas separation
Electric field stops molecular wriggling and boosts natural gas separation in porous crystal
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ResearchFirst boron–tellurium double bond captured
Unusual molecule features shortest boron bond to one of the rarest metals on Earth
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ResearchHeavy elements forged by cataclysmic cosmic collision
First sighting of two neutron stars merging reveals how heavy elements are synthesised
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ResearchBright future for trace water analysis
MOF-based material has detection limit as low as traditional Karl Fischer titration
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ResearchImmense oganesson projected to have no electron shells
Theory predicts that element 118 would be surrounded by a smear of electrons
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ResearchChemists reinvent the wheel
Symmetrical gold and niobium cluster with unusually short Nb–Nb bond
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PodcastSodium dichromate
Discover the compound at the heart of a multi-million dollar legal case and an Oscar–winning role for Julia Roberts
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ResearchAll-metal ion mimics carbonate
Seven month reaction delivers peculiar tin–bismuth anion that is first solution-stable all-metal carbonate analogue
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Podcasttert-Butyl lithium or t-BuLi
A pyrophoric reagent that remains one of chemistry’s staples and the liquid salts that can tame its wild reactivity
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ResearchHunt for element 119 to begin
Japan and the US team up to start the next row of the periodic table
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OpinionSolving the technetium medical isotope shortage
The UK has a solution to the potential shortage of technetium-99m – but that’s no reason to be complacent about leaving Euratom
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NewsWarnings that radiochemistry is dying
Critical nuclear know-how is dwindling as the younger generation avoid this vital field
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ResearchThe big bang theory inspires discovery of new compound BaZnGa!
Fictional physicist Sheldon Cooper’s catchphrase has been brought to life in the lab
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ResearchSeaborg's americium dispute put to bed 60 years later
Hotly debated historical brouhaha that centred on the element’s covalency may have been solved
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OpinionNickel catalyst couples alcohols and carbon dioxide
Flexibility and low cost make nickel a firm favourite in catalysis
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ResearchChemists unravel why humans aren’t constantly bursting into flames
Strong π-bonding holds the secret to taming dioxygen diradicals
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ResearchScientists get charged up over titanium dioxide
Groups debate usefulness of conventional +4 titanium oxidation state compared to +2.5 charge state
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Research+2 lead hydride is world’s first
Organo-lead compound completes +2 hydride puzzle of heavy group 14 elements
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ResearchAnion confounds expectations with its electron-loving nature
A boron cluster is the first example of a dipole-distinguishing electrophilic anion