Inorganic chemistry – Page 3
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Research
Electrochemical wizardry conjures nitrate at room temperature from air
Process could cut the huge carbon footprint of fertiliser production
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Research
Redox reactions ‘mine’ old fluorescent light bulbs for europium
In just three simple steps rare earth element can be recovered, avoiding ‘ecologically devastating’ mining
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Research
Dimetallocene with two different metal centres synthesised for the first time
Molecule first theorised 20 years ago created in the lab
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Research
New metal-free MOFs show early promise for nuclear chemistry
Discovery of counterparts to metal-organic frameworks guided by crystal-structure prediction tools
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Research
Promethium bond length completes picture of the size of lanthanides’ atoms
Study fills one of the last gaps in our knowledge of the periodic table
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Opinion
The 1920s chemists who thought they’d achieved the alchemists’ dream
The now-forgotten transmutation controversy hung on apparent evidence of mercury transforming into gold
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Research
Single atom layer of gold produced for the first time
Goldene synthesised via etching technique used in Japanese knife-making
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Research
Iodide addition could make high energy lithium-sulfur batteries commercially viable
Next generation batteries given self-healing properties and vastly improved electronic conductivity by sulfur iodide inclusion
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Research
Debate surrounding amorphous selenium’s structure rumbles on
New evidence suggests that amorphous selenium forms eight-membered rings, but some researchers believe the results are inconclusive
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Research
Boron cluster family breaks electron counting rules
Rare structures have unusual deltahedral shapes
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Opinion
High entropy or just complex?
Several elements mixed in a single crystal phase isn’t necessarily a high entropy material
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Feature
Marvellous mixtures of metals
High entropy alloys, with anywhere from five or more different metals, have unusual properties and could find use in a variety of high-tech applications. Clare Sansom reports
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Research
Plutonium to carbon double bond a first
Findings offer insight into differences in chemical reactivity between actinides and lathanides
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Research
Unusual bridging fluorine discovered in one-of-a-kind interhalogen ion
Similarity to MgAgAs crystal structure takes researchers by surprise
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Opinion
A milestone year
2024 is set to be a special year for Chemistry World because it’s 20 years since we published our first issue
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News
The story of how the most successful US–Russia scientific collaboration collapsed
Five jointly discovered superheavy elements completed the eighth row of the periodic but then Russian revanchism reared its head
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Research
Robotic chemistry lab joins forces with Google AI to predict then make new inorganic materials
Algorithm discovered more than 2 million inorganic structures
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Feature
Reaching into the non-covalent toolbox
Alongside supramolecular stalwarts, budding bonding forms are vying to be valuable, finds Andy Extance
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Feature
When a bond gets too extreme
Chemical bonds are part of the way chemists rationalise the behaviour of atoms in the conditions of the world around them. Tim Wogan looks at how they are affected when those conditions change
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Research
Scientists may have detected exotic nitrogen-9 isotope
Nuclei would be the first to decay by the emission of five protons