Inorganic chemistry – Page 4
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ResearchRedox-fluid ligand stabilised as triradical for the first time
Complex with unusual spin state has implications for single-molecule magnets
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ResearchIntermediate considered ‘too reactive to isolate’ finally tamed
Nitrene species stabilised for three days with careful choice of substituent
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ResearchHow many molecules of water does it take to dissociate HCl? It’s complicated
New work sheds lights on when hydrogen chloride turns into hydrochloric acid
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ResearchElectrochemical wizardry conjures nitrate at room temperature from air
Process could cut the huge carbon footprint of fertiliser production
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ResearchRedox reactions ‘mine’ old fluorescent light bulbs for europium
In just three simple steps rare earth element can be recovered, avoiding ‘ecologically devastating’ mining
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ResearchDimetallocene with two different metal centres synthesised for the first time
Molecule first theorised 20 years ago created in the lab
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ResearchNew metal-free MOFs show early promise for nuclear chemistry
Discovery of counterparts to metal-organic frameworks guided by crystal-structure prediction tools
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ResearchPromethium bond length completes picture of the size of lanthanides’ atoms
Study fills one of the last gaps in our knowledge of the periodic table
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OpinionThe 1920s chemists who thought they’d achieved the alchemists’ dream
The now-forgotten transmutation controversy hung on apparent evidence of mercury transforming into gold
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ResearchSingle atom layer of gold produced for the first time
Goldene synthesised via etching technique used in Japanese knife-making
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ResearchIodide addition could make high energy lithium-sulfur batteries commercially viable
Next generation batteries given self-healing properties and vastly improved electronic conductivity by sulfur iodide inclusion
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ResearchDebate surrounding amorphous selenium’s structure rumbles on
New evidence suggests that amorphous selenium forms eight-membered rings, but some researchers believe the results are inconclusive
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ResearchBoron cluster family breaks electron counting rules
Rare structures have unusual deltahedral shapes
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OpinionHigh entropy or just complex?
Several elements mixed in a single crystal phase isn’t necessarily a high entropy material
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FeatureMarvellous mixtures of metals
High entropy alloys, with anywhere from five or more different metals, have unusual properties and could find use in a variety of high-tech applications. Clare Sansom reports
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ResearchPlutonium to carbon double bond a first
Findings offer insight into differences in chemical reactivity between actinides and lathanides
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![[Br4F21]- index image](https://d2cbg94ubxgsnp.cloudfront.net/Pictures/100x67/1/7/3/532173_br4f21indeximage_49094.jpg)
ResearchUnusual bridging fluorine discovered in one-of-a-kind interhalogen ion
Similarity to MgAgAs crystal structure takes researchers by surprise
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OpinionA milestone year
2024 is set to be a special year for Chemistry World because it’s 20 years since we published our first issue
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NewsThe story of how the most successful US–Russia scientific collaboration collapsed
Five jointly discovered superheavy elements completed the eighth row of the periodic but then Russian revanchism reared its head
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ResearchRobotic chemistry lab joins forces with Google AI to predict then make new inorganic materials
Algorithm discovered more than 2 million inorganic structures