Inorganic chemistry – Page 5
-
ResearchFirst examples of odd-electron σ bonds for aluminium and gallium
Two new complexes with unusual two-centre/one-electron σ bonds are added to the group 13 family
-
ResearchStrange new bonds found hiding in plain sight in common organometallics
Collective interactions are proof that there’s more to bonds than just connecting neighbouring atoms
-
ResearchPepto-Bismol compound’s structure unveiled after 120 years
Electron microscopy triumphed over x-ray crystallography as century-old structural puzzle around bismuth subsalicylate is finally solved
-
OpinionWilliam Knox, the only Black supervisor in the Manhattan Project
The story of the Knox family is one of education overcoming adversity, finds Kit Chapman
-
ResearchThis metal triangle seems to defy definition – is it aromatic or not?
Discussion around thorium ring’s aromaticity has chemists questioning if we should stop calling metal clusters aromatic
-
ResearchThe closest chemists have ever got to an inorganic ferrocene
Compound comprises an iron ion sandwiched between two aromatic phosphorus squares
-
ResearchNeptunium complex’s triple bond challenges actinide bonding assumptions
Elusive transuranic mono(oxo) complex isolated for the first time
-
OpinionBecause it isn’t there
Why do chemists do what they do? The underlying philosophy for many of us is the same as it has been for centuries
-
ResearchMetal switches on iodine’s σ-hole
Iodine’s halogen-bonding ability can be switched on and off by creating ruthenium sandwich
-
ResearchDilanthanide complexes smash record for strongest single-molecule magnet
Complexes featuring first ever lanthanide–lanthanide bond could offer way to make powerful new permanent magnets
-
ResearchShortest-lived and lightest magnesium isotope ever too unstable to even attract electrons
Magnesium-18 cation has a fleeting half-life of 3 billion trillionths of a second
-
FeatureHow elements are made beyond the stars
Tim Wogan looks at what recent astronomical discoveries have added to our understanding of stellar nucleosynthesis, and the mysteries that remain
-
ResearchBerkelium complex opens door for future nuclear recycling
Complex is only the sixth ever created
-
ResearchMashed magnesium used to prepare Grignards without worrying about air
Mechanochemical method avoids inert gas and dry solvents in classic organometallic reaction
-
ResearchRare red californium sandwich pushes frontier of isolable molecules
Researchers rehearsed metallocene’s synthesis with other elements before using just two milligrams of the precious radioactive actinide
-
ResearchUnsupervised machine-learning tool could accelerate catalyst discovery
The approach was able to identify phosphine ligands that may form dinuclear palladium(I) complexes using only five experimental data points
-
ResearchUranium’s strong covalent bond breaks periodic table predictions
Actinide’s unusual covalency could explain its ability to fix nitrogen
-
ResearchWater splitting electrocatalyst made from unconventional alloy containing 14 elements
Simple dealloying process creates complex nanoporous alloy
-
ResearchSemimetal study links spiral magnetism to Weyl fermions
Findings may help explain spatial modulations seen in the magnetism of other rare earth intermetallic compounds
-
ResearchActinide aromaticity defies predictions
First σ-aromatic thorium cluster extends σ aromaticity to periodic table’s heaviest elements