Inorganic chemistry – Page 6
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FeatureReaching the molecular limit of magnetic memory
Clever chemistry could help computers cram even more data onto their hard drives. Rachel Brazil reports on single-molecule magnets
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ResearchMacrocyclic NHC ligands serve up trio of new actinide sandwich complexes
Delocalised, anionic macrocyclic NHCs with unusually strongly σ-donation set to expand suite of stable organometallic complexes with f block cations
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OpinionIda Noddack and the trouble with element 43
The German chemist discovered one element and may have been the first to suggest nuclear fission – but her legacy is troubled, as Rachel Brazil discovers
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ResearchCalculations predict first quadruple bond between a transition metal and silicon
Silicon–ruthenium interaction adds to flurry of research on multiple bonds
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ResearchLightest uranium isotope yet reveals nuclear stability secrets
Discovery offers new insight into isotopic stability seen at ‘magic numbers’
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NewsTributes paid as Royal Society of Chemistry past president Eddie Abel dies
Organometallic chemistry giant passes away aged 89
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ResearchComputational study finds fluorine in flatland
Proposed planar clusters contain fluorine atoms and group 13 elements
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ResearchExotic bond takes computational chemists by surprise
New results could help to solve the dispute around the strange Na–B bond in NaBH3–
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ResearchThree-centre single-electron bond caught in a cage
Fullerene cage stabilises bond never before seen in lanthanide chemistry
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ResearchNew definition of electronegativity fixes flaws left by Linus Pauling
Revised version of Pauling’s formula enables better predictions for problem systems such as metal-containing molecules
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ResearchFour-electron transfer is a first for f-element chemistry
Uranium (II) systems shown to effect reduction of azobenzene to yield a bis(imido) uranium (VI) complex
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ResearchCadmium cyanide surprises chemists by shrinking when irradiated with x-rays
Contraction expands potential applications for inorganic materials
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ResearchOrganometallic manganese cluster resembles nesting dolls
Researchers make an intricate structure with a strong magnetocaloric effect
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ResearchDouble bond metathesis extended to germanium compounds
Partner swapping reaction carried out with digermene compounds, with no need for a catalyst
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ResearchCations pairs exhibit surprising attraction
‘Complex of complexes’ containing silver and iodonium ions experience an unprecendented interaction
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ResearchHalf the world’s supply of element 99 used to reveal its chemical secrets
Scientists explore einsteinium’s unusual chemistry using less than 200 nanograms of the precious and highly radioactive material
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ResearchHoles cause sodium nitride to behave like a metal
Clathrate’s strange metallic nature caused by electronically active cavities
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ResearchFirst flat tetravalent silicon stabilised by metals and aromaticity
Chemists make stable compound featuring a silicon atom that forgoes tetrahedral geometry
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ResearchBeryllole is the first alkaline earth metal antiaromatic molecule
Metallacyclopentadiene is the first beryllium compound to engage in π system chemistry
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ResearchHeavy-metal cluster sets size record for metal aromaticity
12 bismuth ring creates ‘substantial’ π aromaticity with only two aromatic electrons