Inorganic chemistry – Page 8
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ResearchGiant crystal lattice is mesoporous but not a MOF
Non-covalent network has the largest unit cell among non-MOFs
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ResearchFirst fleeting glimpse of metallic water
Electron doping briefly turns water into golden metal
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![An image showing a [M2(BzN6-Mes)]n− complex](https://d2cbg94ubxgsnp.cloudfront.net/Pictures/100x67/4/0/8/514408_index_128835.jpg)
ResearchMetal sandwich stabilises first benzene triplet-state aromatic
Benzene diradical dianion is the first monocyclic molecule that’s Baird aromatic in the ground state
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ResearchChloride ion central to first synthesis of a siladodecahedrane
Three-step synthesis creates a platonic solid out of silicon
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ResearchFun with f-elements
Working with lanthanides and actinides may be challenging, but David Mills says the field is ripe for discovery
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FeatureSupermetals versus superbugs
With pathogenic bacteria rapidly overcoming our arsenal of organic antibiotics, James Mitchell Crow asks if it is time to revisit metal-based antimicrobials
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ResearchScientists uncover pitfalls of letting algorithms determine crystal structures
Chemists warn not to blindly trust x-ray crystallography software after finding and correcting mistakes in iodine azide structures
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ResearchMore metallomimetic chemistry from boron
One boron atom bonds like a transition metal in two different ways
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NewsApparent plagiarism leads Elsevier to retract periodic table book
Chemist contacted by suspicious Wikipedia editor finds that large sections were lifted from online encyclopaedia
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FeatureReaching the molecular limit of magnetic memory
Clever chemistry could help computers cram even more data onto their hard drives. Rachel Brazil reports on single-molecule magnets
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ResearchMacrocyclic NHC ligands serve up trio of new actinide sandwich complexes
Delocalised, anionic macrocyclic NHCs with unusually strongly σ-donation set to expand suite of stable organometallic complexes with f block cations
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OpinionIda Noddack and the trouble with element 43
The German chemist discovered one element and may have been the first to suggest nuclear fission – but her legacy is troubled, as Rachel Brazil discovers
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ResearchCalculations predict first quadruple bond between a transition metal and silicon
Silicon–ruthenium interaction adds to flurry of research on multiple bonds
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ResearchLightest uranium isotope yet reveals nuclear stability secrets
Discovery offers new insight into isotopic stability seen at ‘magic numbers’
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NewsTributes paid as Royal Society of Chemistry past president Eddie Abel dies
Organometallic chemistry giant passes away aged 89
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ResearchComputational study finds fluorine in flatland
Proposed planar clusters contain fluorine atoms and group 13 elements
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ResearchExotic bond takes computational chemists by surprise
New results could help to solve the dispute around the strange Na–B bond in NaBH3–
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ResearchThree-centre single-electron bond caught in a cage
Fullerene cage stabilises bond never before seen in lanthanide chemistry
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ResearchNew definition of electronegativity fixes flaws left by Linus Pauling
Revised version of Pauling’s formula enables better predictions for problem systems such as metal-containing molecules
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ResearchFour-electron transfer is a first for f-element chemistry
Uranium (II) systems shown to effect reduction of azobenzene to yield a bis(imido) uranium (VI) complex