Inorganic chemistry – Page 9
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Research
New type of bond is the first to defy actinide contraction trend
Bonds discovered in metallacycles are unique to the 5f elements
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Opinion
Jimmy Robinson and the atom bomb elements
USAF pilots flew into mushroom clouds to bring back samples that turned out to contain new elements – one of them didn’t make it home
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Research
A whole new world for barium, including first ever non-ionic barium fluoride
Ligand tames barium, making precursor to first barium–tin and first molecular barium–fluorine bond
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Research
Metal complexes outperform organics in antimicrobial analysis on crowdsourced compounds
Could this study prompt drug developers to rethink their reluctance to making metal-based pharmaceuticals?
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Research
Textbook structure rules formulated by Linus Pauling 90 years ago prove unreliable
Just 13% of 5000 oxides found to fulfil all five coordination geometry predictions
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Research
Light-harvesting clusters and titanium dioxide cooperate to fix nitrogen
Atomically precise metal clusters continue to gather momentum by catalysing the production of ammonia
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Research
Metallic hydrogen reveals itself under mounting pressure
Robust data help close in on prized room temperature superconductor
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News
Bird droppings to help cut the crap in graphene doping papers
Dramatic illustration shows there’s little value in doping graphene electrodes to make better water splitting catalysts
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Research
First benzene-mimicking molecule made entirely from palladium
Palladium hexagon is a rare example of all-metal aromatic nanocluster
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Research
Rhenium plays starring role in bond movie
Controllable energy input from transmission electron microscope captures atoms dissociating and recombining
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Podcast
Cobalt oxide
From ancient Egyptian pottery to distinctive blue bottles, cobalt oxide has been providing ‘chemically and artistically perfect’ pigments for centuries
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Feature
Polly Arnold’s diversity of interests
Kit Chapman asks the champion of actinide chemistry and diversity in science what comes next as she starts her new role at a US national lab
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Research
Mystery around ‘stealthy’ surfactants deepens as study raises more questions
Simple explanation for why inorganic boron clusters behave like organic surfactants doesn’t convince everyone
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Research
Semiconductive properties see subvalent silver oxide contravene textbook rules
Extreme synthetic conditions create material with a seemingly implausible electron count
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Research
Inorganic fragment library ready to help drug discoverers reach neglected regions of chemical space
A new approach to fragment-based drug design
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Research
Rare subvalent compound sits on the fence between semiconductors and intermetallics
Liquid indium solvent and sulfur-poor conditions allow scientists to create a new subchalcogenide
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Research
Uranium-reducing electrode cleans up groundwater
Electrochemical technique could limit spread of uranium at contaminated sites
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Research
Intense sound fields make mercury react with water
After nearly a century, scientists can explain why a grey cloud forms when mercury and water are sonicated
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Research
Trigold anion is first example of strange twisted aromaticity
A blue tin–gold cluster is the first to show in-plane σ-Möbius aromaticity
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Research
Double aromaticity found in boron analogue of metallabenzene
Boron–rhenium cluster is both σ- and π-aromatic