Inorganic chemistry – Page 9
-
ResearchGiant crystal lattice is mesoporous but not a MOF
Non-covalent network has the largest unit cell among non-MOFs
-
ResearchFirst fleeting glimpse of metallic water
Electron doping briefly turns water into golden metal
-
![An image showing a [M2(BzN6-Mes)]n− complex](https://d2cbg94ubxgsnp.cloudfront.net/Pictures/100x67/4/0/8/514408_index_128835.jpg)
ResearchMetal sandwich stabilises first benzene triplet-state aromatic
Benzene diradical dianion is the first monocyclic molecule that’s Baird aromatic in the ground state
-
ResearchChloride ion central to first synthesis of a siladodecahedrane
Three-step synthesis creates a platonic solid out of silicon
-
ResearchFun with f-elements
Working with lanthanides and actinides may be challenging, but David Mills says the field is ripe for discovery
-
FeatureSupermetals versus superbugs
With pathogenic bacteria rapidly overcoming our arsenal of organic antibiotics, James Mitchell Crow asks if it is time to revisit metal-based antimicrobials
-
ResearchScientists uncover pitfalls of letting algorithms determine crystal structures
Chemists warn not to blindly trust x-ray crystallography software after finding and correcting mistakes in iodine azide structures
-
ResearchMore metallomimetic chemistry from boron
One boron atom bonds like a transition metal in two different ways
-
NewsApparent plagiarism leads Elsevier to retract periodic table book
Chemist contacted by suspicious Wikipedia editor finds that large sections were lifted from online encyclopaedia
-
FeatureReaching the molecular limit of magnetic memory
Clever chemistry could help computers cram even more data onto their hard drives. Rachel Brazil reports on single-molecule magnets
-
ResearchMacrocyclic NHC ligands serve up trio of new actinide sandwich complexes
Delocalised, anionic macrocyclic NHCs with unusually strongly σ-donation set to expand suite of stable organometallic complexes with f block cations
-
OpinionIda Noddack and the trouble with element 43
The German chemist discovered one element and may have been the first to suggest nuclear fission – but her legacy is troubled, as Rachel Brazil discovers
-
ResearchCalculations predict first quadruple bond between a transition metal and silicon
Silicon–ruthenium interaction adds to flurry of research on multiple bonds
-
ResearchLightest uranium isotope yet reveals nuclear stability secrets
Discovery offers new insight into isotopic stability seen at ‘magic numbers’
-
NewsTributes paid as Royal Society of Chemistry past president Eddie Abel dies
Organometallic chemistry giant passes away aged 89
-
ResearchComputational study finds fluorine in flatland
Proposed planar clusters contain fluorine atoms and group 13 elements
-
ResearchExotic bond takes computational chemists by surprise
New results could help to solve the dispute around the strange Na–B bond in NaBH3–
-
ResearchThree-centre single-electron bond caught in a cage
Fullerene cage stabilises bond never before seen in lanthanide chemistry
-
ResearchNew definition of electronegativity fixes flaws left by Linus Pauling
Revised version of Pauling’s formula enables better predictions for problem systems such as metal-containing molecules
-
ResearchFour-electron transfer is a first for f-element chemistry
Uranium (II) systems shown to effect reduction of azobenzene to yield a bis(imido) uranium (VI) complex