Main group chemistry – Page 5
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ResearchBizarre bimetallic compounds break C–F bonds
First ever molecular Mg–Al bond constructed in study that reveals main group metal–metal bonds can readily react with aromatic fluorine
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Research2D gallium stripped from molten metal
Gallenene is the first atomically thin material made by exfoliating a liquid metal
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ResearchGermanium analogue of cyclobutadiene isolated
Polar Jahn–Teller distortion stabilises unusual molecule
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ResearchMaterial containing perfectly planar octacoordinate titanium predicted
Titanium falls flat in an eight-membered boron ring
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ResearchFirst boron–tellurium double bond captured
Unusual molecule features shortest boron bond to one of the rarest metals on Earth
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ResearchAll-metal ion mimics carbonate
Seven month reaction delivers peculiar tin–bismuth anion that is first solution-stable all-metal carbonate analogue
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ResearchThe big bang theory inspires discovery of new compound BaZnGa!
Fictional physicist Sheldon Cooper’s catchphrase has been brought to life in the lab
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ResearchChemists unravel why humans aren’t constantly bursting into flames
Strong π-bonding holds the secret to taming dioxygen diradicals
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ResearchScientists get charged up over titanium dioxide
Groups debate usefulness of conventional +4 titanium oxidation state compared to +2.5 charge state
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Research+2 lead hydride is world’s first
Organo-lead compound completes +2 hydride puzzle of heavy group 14 elements
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Research‘Pink phosphorus’ caged in carbon nanotubes
Highly reactive white phosphorus seen linking up to make new 1D form on way to red allotrope of the element
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ResearchCopper brings glow to triple-bonded boron
Unexpected reaction between boron–boron triple bond and transition metals revealed
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ResearchPlutonium gets another oxidation state added to its arsenal
New +2 oxidation state fills hole in transuranium element chemistry
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ResearchSecret of dinitrogen triple bond's strength unpicked
Scientists find an unexpected explanation for the strength of nitrogen–nitrogen triple bonds
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ResearchInert helium reacted with sodium in chemistry first
Spartan field of helium chemistry given a lift with new sodium compound
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ResearchStable polynitrogen synthesis first blows everyone away
Creation of five-membered aromatic nitrogen ring opens door to new highly energetic rocket fuels and explosives
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ResearchBismuth superconductor leaves theory up in the air
Discovery of superconductivity at exceptionally low temperatures confounds current understanding of the phenomenon
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ResearchTheory finds window for astatine species’ existence
Researchers take investigation of iodine–astatine–bromine trihalogen anion into the lab
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ResearchMicroscopy reveals secret of beryl’s iron heart
Discovery of metal stuffed channels in mineral family that includes emerald and aquamarine points way to tuning the material’s colour
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ResearchA new recipe for black phosphorus
Chemists develop a new method to produce supported black phosphorus with applications in catalysis