All Matter articles – Page 27
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Research
Record NMR shift in metal-bound phosphorus
Second record for iron complex as chemical shift beyond –10,000ppm discovered in phosphorus atoms directly bound to the metal
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Research
Peptide superstructures speed up Michael reaction
A tripeptide that self-assembles into a supramolecular fibres accelerates an asymmetric benchmark reaction by up to 74%
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Ultraphosphates break decades-old anti-branching rule
Discovery of elusive branched phosphates’ unexpected stability means they could have played a role in prebiotic chemistry
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First vortex beam made entirely of atoms
Twisting atoms’ quantum mechanical wave function into a helix could reveal insights into atom–matter interactions
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Liquid crystals under pressure create squid-like camouflage
Pneumatic membranes trigger full-spectrum colour shifting on demand
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Method to make unusual oligonucleotides could be a boon for gene therapy drugs
Synthesis can insert unusual linkages into DNA molecules while rivalling industry standard chemistry in speed and efficiency
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Business
Chemours under fire for trying to exempt fluorochemicals from EU regulation
European Court of Justice will rule on whether GenX chemicals should be listed as substances of very high concern
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Research
Giant molecular cage protects plastic-eating enzyme
Caged protein withstands temperatures much hotter than its usual melting point and becomes 1000 times more resistant to solvents
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Research
First fluoronium crystal solves structure controversy
X-ray analysis of elusive cation finally proves it to be a symmetric near-covalent structure, not a carbocation
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Research
Heavy metal proteins are the secret weapon in ant bites
Protein-rich biomaterials containing zinc, manganese, copper and bromine allow ants, crabs and scorpions to pack more punch for their size
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Research
Flip battery sideways for NMR studies
By turning button batteries on their side they can be studied by nuclear magnetic resonance without removing their metal casing
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Eggshell-ent MOFs made from sustainable precursors
Green starting materials for calcium-based frameworks
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Enantioselective synthesis of elusive chiral nitrogen compounds discovered by chance
An ‘elegant and simple’ way to make nitrogen stereocentres by supramolecular recognition
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Machine learning accurately predicts RNA structures using tiny dataset
Development could lead to better understanding of RNA and new medicines
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Research
Overreliance on cryocooled protein structures may compromise computational structure-based drug design
Scientists behind first of its kind study encourage more researchers to analyse protein structures at room temperature
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Water splitting electrocatalyst made from unconventional alloy containing 14 elements
Simple dealloying process creates complex nanoporous alloy
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Research
Chemical definition of brine as water could help clear up Chile’s lithium controversy
As evidence grows that lithium mining damages water sources, reclassifying brine as water – rather than as mineral – could empower Indigenous communities to protect their rights and convince mining companies to act more responsibly
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Business
Massive fire at UK polyurethanes plant
One worker remains missing a week after Leamington Spa incident
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Research
Electrons in zinc’s filled 3d orbitals can participate in chemical reactions
Super electrophilic trianions accept three additional electrons to support zinc in a +3 oxidation state