All Matter articles – Page 29
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Research
Giant crystal lattice is mesoporous but not a MOF
Non-covalent network has the largest unit cell among non-MOFs
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Research
There was more than simple oxygen depletion to ancient mass extinction event
Thallium isotopes reveal that rapid swings in ocean oxygenation preceded the events that wiped out 90% of species 250 million years ago
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Research
Heavy-atom quantum tunnelling catalysed with Lewis acids
Lewis acid–base interactions found to increase quantum tunnelling rates of rearrangement reaction
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Research
Machine-learning tool performs stereochemical assignments on SPM images
Identifying chiral centres on SPM images with machine-learning tools only takes a few hours and could save researchers time
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Research
First fleeting glimpse of metallic water
Electron doping briefly turns water into golden metal
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Research
Safer fluorination process developed using flow electrochemistry
Automated system for constructing carbon–fluorine bonds quenches fluorine compounds to reduce exposure and risk to lab chemists
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Research
Metal sandwich stabilises first benzene triplet-state aromatic
Benzene diradical dianion is the first monocyclic molecule that’s Baird aromatic in the ground state
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Research
Levitating glass bead closes in on quantum mechanics' fundamental limit
Two different methods track position and speed of an ultracold glass sphere with a precision that comes close to the limit set by Heisenberg’s uncertainty principle
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Research
Observing the life and death of a single excited-state molecule
Individual pentacene’s triplet lifetime – and how it is cut short by a nearby oxygen – measured with atomic resolution
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Research
Transient spectroscopy sheds light on elusive photoredox process
Study confirms mechanism of sensitisation-initiated electron transfer reaction following extended debate
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Research
Chloride ion central to first synthesis of a siladodecahedrane
Three-step synthesis creates a platonic solid out of silicon
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Feature
The search for the grand unification of aromaticity
Researchers have been trying to find a full definition of aromaticity for almost two centuries, and yet keep discovering new types
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Research
Clever ring-strain engineering creates infinitely recyclable polymer – but are they ready to compete with commercial plastics?
Ultra-stable polymer that can be broken down into its feedstock could be a foot in the door to a circular plastics economy
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Research
Electrocatalysis offers green alternative for ethylene purification
Copper catalysts enable selective and efficient acetylene reduction at ambient conditions
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Research
Glass folded into intricate origami shapes
Embedding silica particles into a polymer creates a bendable material that can be converted into glass
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Research
Newly discovered marine compound is in a super-carbon-chain league of its own
Isolated from algae, Benthol A has 35 stereocentres
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Research
Molecular light switch speeds up tricky cyclodextrin synthesis
Reaction could lower cost of useful macrocycle
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Research
Aluminium compound deconstructs sulfur hexafluoride in minutes
Method turns potent greenhouse gas into useful synthetic reagents
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Research
Tentacled droplets swim with stored heat energy
Microdroplets with retractable tendrils could help researchers understand how bacteria move