All Matter articles – Page 33
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Research
The whitest white paint ever is also the coolest
New paint formulation that reflects up to 98.1% of sunlight can rival the cooling power of air conditioners
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Research
Computational study finds fluorine in flatland
Proposed planar clusters contain fluorine atoms and group 13 elements
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Exotic bond takes computational chemists by surprise
New results could help to solve the dispute around the strange Na–B bond in NaBH3–
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Research
Three-centre single-electron bond caught in a cage
Fullerene cage stabilises bond never before seen in lanthanide chemistry
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Research
Ion trapping desalination membrane fishes out valuable materials
Selectively trapping toxic or useful ions could reduce toxicity of brine waste and offset costs
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Greener plastic made from leftover fish guts and bones
Canadian researchers make a polyurethane-like polymer from oils
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Easy and efficient entropies for everyone
Conformational analysis package gains ability to automatically evaluate entropy
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New definition of electronegativity fixes flaws left by Linus Pauling
Revised version of Pauling’s formula enables better predictions for problem systems such as metal-containing molecules
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Feature
Drink, drugs and disease: the chemistry of breath tests
From roadside tests to diagnosing Covid-19, Clare Sansom looks at how breathalysers have developed
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Research
Unstable silicon double bonds tamed in polymers made on metals
Process could ‘open the door’ to new electronic materials
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Four-electron transfer is a first for f-element chemistry
Uranium (II) systems shown to effect reduction of azobenzene to yield a bis(imido) uranium (VI) complex
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Research
New injection moulding technique allows glass to be cast in any shape
Energy costs of producing glass can also be cut by as much as 40%
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Research
Chemists reconsider the impact of through-space effects
Through-space electrostatic effects are shown to be dominant in certain radical reactions, where previously through-bond interactions were thought to determine reaction rate
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Research
Ingestible COF that delivers insulin could help diabetics duck injections
When blood glucose levels are high, glucose displaces insulin loaded in the framework
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Research
Discovery of aromatics in interstellar cloud shakes up astrochemistry
Two polycyclic aromatic hydrocarbon molecules found in a cold, dark space suggests they are more widespread than was thought
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Research
Photocatalytic process picks out precious metals from waste electronics
Silver, gold, platinum and palladium can be retrieved sequentially from circuit boards and catalytic convertors
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Research
Supramolecular cage unlocks mild aldehyde reduction strategy
Computational analysis reveals how encapsulation stabilises protonated oxocarbenium ion of furfural, which makes the carbonyl moiety easier to reduce
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Research
Plasmon-assisted click reaction reverses typical relationship between temperature and rate
Decrease in temperature seems to extend lifetime of plasma-induced excited states, which increases probability of reaction occurring
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Research
Programmed cyclodextrin synthesis picks out specific molecule from 117,655 possibilities
Thioacetate orienting group allows for fine-tuned cyclodextrin functionalisation
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Research
Tandem catalysis and smart design offer new route to polypropylene plastic
Selective combustion of hydrogen by-product improves oxidative propane dehydrogenation yields