All Matter articles – Page 43
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Business
Ineos to buy BP petrochemicals businesses for $5bn
Deal covers 14 acetyls and aromatics manufacturing plants and 10 joint ventures
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Research
Excited state potential energy curves reignite diatomic carbon’s bond order conundrum
Molecular orbital theory-based approach backs quadruple bond
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Research
New bond discovered among spodium elements zinc, cadmium and mercury
Group 12 joins the σ-hole interaction family with spodium bonds
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Research
Mechanical force used to trigger isomerisation in 3D molecule
An atomically sharp scanning tunnelling microscope tip has been used to control the isomerisation of a butterfly-shaped compound
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Opinion
Can computational chemistry benefit from blockchain?
It could be a new paradigm in safeguarding science, but it might just tie our hands
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Research
Bright blue radical lives on for months in chicken feed and urea solution
Deep eutectic solvents can tame methyl viologen radical used in self-dimming windows
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Research
Computational method challenges NMR metabolomics dogma
Macromolecule signal suppression without the loss of quantitative small molecule information finally achieved with mathematical trick
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Feature
Metalloenzyme mastery
There are natural metalloenzymes that make difficult chemistry look easy. James Mitchell Crow talks to the bioinorganic chemists figuring out how to copy them
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Research
Ultrasound makes nano-waves, generating ‘green’ radicals
Chemical engineers use high-frequency soundwaves to dissociate water without catalysts or electrolytes
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Research
‘Godzilla’s gym socks’ molecules' stench tamed by halogen bond
Russian researchers have found a way to eliminate the odour of some of the worst-smelling – but very useful – compounds in chemistry
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Research
First reaction on carbon nanobelts creates largest ever iptycene
Diels-Alder reactivity signals that carbon nanobelts could be useful building blocks for large macrocyclic carbon-based structures
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Research
Microfluidic electrochemistry delivers radical coupling breakthrough
Interelectrode gap engineered so that diffusion outpaces radical decomposition
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Research
Algorithm devises synthetic contingency plans for Covid-19 drug
Retrosynthesis software tool can identify multiple synthetic routes that use inexpensive and diverse starting materials while avoiding patented methods
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Research
Beautiful molecules ring up with a purpose
How Stephen Goldup used his experience in organic synthesis to find a supramolecular niche
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Research
Solvated electrons’ metallic transition resolved with spectroscopy
First photoelectron spectra of electrolyte-to-metal transition in ammoniated electrons could lead to metallic water
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Research
Strange hexagonal form of table salt discovered
Predicted by an evolutionary algorithm, the first hexagonal sodium chloride was made on a diamond surface
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Research
New kind of heterocycle made in just one easy step
Simple synthesis makes once inaccessible class of fused seven-membered ring system
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Opinion
Barbara Low, penicillin and the protein pi helix
Mike Sutton celebrates the remarkable career of a female crystallographer, once mistaken for the tea-lady
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Research
Molecular machine enables polyrotaxane synthesis with unprecedented precision
Artificial pumps can add up to 10 molecular rings onto polymer dumbbells in a controlled manner