All Matter articles – Page 60
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Research
Brown ring molecule defies the very definition of oxidation state
Classic nitrate test compound isolated for the first time challenges chemistry governing body’s ideas on oxidation state
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Research
Can catalysis save us from our CO2 problem?
We need to start seeing carbon dioxide as as a valuable raw material to make chemicals, fuels and even food
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Opinion
‘Coffee machine’ synthesiser’s first steps
Cartridge-based machine enables non-experts to make heterocycles
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Research
Bond order through a molecular orbital lens
Study computes diatomic bond orders across the periodic table and reveals new bonding insights
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Feature
Iridium and the demise of the dinosaurs
Geochemical clues from the Cretaceous period reveal the final days of the terrible lizards
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Research
Curious colours expose f-electron covalency effects
New knowledge overwrites electronic structure assumptions surrounding actinide complexes
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Research
Strange bonds entirely new to chemists predicted in ammonia hydrides
High pressure compound containing bridging hydrogen cations might be found inside Neptune and Uranus
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Research
C–H fluoroalkylation tackles plastic waste
Photocatalytic method that upcycles aromatic polymers could breathe new life into rubbish
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Research
Super-wood offers way to create air con that doesn’t need power
Buildings covered in densified wood ‘super-material’ could cut cooling’s carbon footprint
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Research
Reaching new heights to form a better picture of 3D molecules
Combining two microscopy techniques enables clearer imaging
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Research
Minty-fresh solvent for sustainable cross-couplings
Eucalyptol could replace diethyl ether, DMF, THF and toluene in many synthetic reactions
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Research
New rule predicts stabilising aromaticity in open-shell metal clusters
Magic numbers for jellium aromaticity could help researchers find stable high-spin molecules
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Research
Spin sensor promises atomic-scale magnetic imaging
Nickelocene-tip scanning tunnelling microscope provides measurements to challenge quantum theory calculations
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Research
Quantum mechanical mechanism behind 100-year-old textbook reaction revealed
Study challenges established understanding of Michael addition as it uncovers Pauli repulsion’s key role in halogen catalysis
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Research
Algorithm accurately predicts mechanical properties of existing and theoretical MOFs
Machine learning could speed up the production and use of coordination polymers in industry
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Research
Non-natural system uses covalent base-pairing to transfer information
Template-directed process that replicates non-biological molecules is step towards using evolution to explore chemical space
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News
International Space Station experiments will search for key to soot-free flames
Microgravity research could help to burn fuels more cleanly and cut soot’s contribution to ill health and climate change
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Research
New compounds make dissolving gold simpler and safer
Polypseudohalogen-based ionic liquid offers innovative way to recycle electronics
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Research
Directing group ‘dance’ decorates heterocycles
Reaction that multi-functionalises nitrogen heteroaromatics using a movable directing group has already attracted the attention of industrial chemists
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Research
Bizarre ice XVIII is an oxygen ion crystal swimming in a sea of protons
High pressure superionic form of water may hold clues to behaviour of giant icy planets in our solar system