When the 1996 Nobel prize in chemistry went to the discoverers of C60, or 'buckyballs' as they were affectionately known, the fullerenes suddenly shot to superstar status. And interest in them continues afresh, with researchers in Germany now isolating C5
When the 1996 Nobel prize in chemistry went to the discoverers of C60, or ’buckyballs’ as they were affectionately known, the fullerenes suddenly shot to superstar status. And interest in them continues afresh, with researchers in Germany now isolating C58.
Fullerenes with fewer than 60 carbon atoms become increasingly less stable structurally because the classical shape, akin to a soccer ball where pentagons are surrounded by hexagons, is not sustainable and pentagons must sit next to other pentagons.
Using electron impact ionisation, Manfred Kappes and his team gave positive C58 ions a soft landing on a graphite substrate to produce what Kappes proclaims is ’likely the world’s largest sample of pure C58: about 30 nanograms’.
This ion-beam technique will allow Kappes to ’write’ molecules onto surfaces and then investigate their electronic properties with an eye to making new materials.
Katharine Sanderson
References
A Böttcher et al, Phys. Chem. Chem. Phys., 2004, 6, 5213 <MAN>b413464h</MAN>
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