Organic chemistry – Page 26
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ResearchTrefoil knots steer cancer drug leads in fresh direction
Chemists look to links and knots in the search for new cancer therapies
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ResearchMinty-fresh solvent for sustainable cross-couplings
Eucalyptol could replace diethyl ether, DMF, THF and toluene in many synthetic reactions
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ResearchQuantum mechanical mechanism behind 100-year-old textbook reaction revealed
Study challenges established understanding of Michael addition as it uncovers Pauli repulsion’s key role in halogen catalysis
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ResearchNon-natural system uses covalent base-pairing to transfer information
Template-directed process that replicates non-biological molecules is step towards using evolution to explore chemical space
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NewsInternational Space Station experiments will search for key to soot-free flames
Microgravity research could help to burn fuels more cleanly and cut soot’s contribution to ill health and climate change
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ResearchNew compounds make dissolving gold simpler and safer
Polypseudohalogen-based ionic liquid offers innovative way to recycle electronics
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ResearchDirecting group ‘dance’ decorates heterocycles
Reaction that multi-functionalises nitrogen heteroaromatics using a movable directing group has already attracted the attention of industrial chemists
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ResearchSurprising radical mechanisms of antioxidant polysulfides
Tetrasulfide prevents oxidation of petroleum products through radical reactions
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ResearchConverting waste plastic bottles into jet fuel
Simple three-step process generates minimal waste and diverts plastic from landfill
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ResearchFirst radial-conjugated aromatic that does the twist
Figure-of-eight shaped molecule is the first with a radial π-electron system
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Opinion
Management by numbers
Reducing intellectual processes to metrics runs the risk of people working to the numbers not the goal
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ResearchNew optical sensors can easily detect heavy water
Colorimetric tests could find applications in NMR, photoacoustics and quality control
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ResearchSupple sugars enable smallest cyclodextrins ever
Bridge that connects hydroxyls enables control over ring conformations in synthetic breakthrough
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ResearchPolycyclic hydrocarbons finally make waves
New aromaticity insights could help advance organic electronics
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ResearchFlexible catalyst systems open up nitrile chemistry
One new strategy enantioselectively produces amines from nitriles, and another generates valuable alkenyl nitriles
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NewsIupac names 10 chemistry innovations that will change the world
Nanopesticides, MOFs and 3D bioprinting among potential breakthrough technologies for a sustainable future
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ResearchLigand selector steers C–N cross-couplings down most sustainable path
Tool is step towards strategy that considers reagents and reactants above and below the arrow
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