Organic chemistry – Page 37
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Research
Spaces can be useful
Truly functional MOFs are on the horizon but Susumu Kitagawa saw their potential when they were weak and idle
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Opinion
Natural selection
Bioactive compounds don’t just inspire new synthetic strategies, they’re also the ultimate test
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Opinion
(‒)-Pavidolide B
An innovative approach to making five-membered carbon rings makes for a strikingly short synthesis
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Research
Flash lithiation made safe
Micromixing enables protecting-group-free synthesis of organolithiums
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Webinar
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Research
Purple crystals boast first aluminium double bond
Aluminium analogue of an alkene completes series of double-bonded boron group elements
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Research
Helicene twists aromaticity to its limit
Six-pronged molecule contains the most twisted and least aromatic benzene ring found yet
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Research
Route to fiendishly complex marine molecule cut in half
Shortcut to promising natural product already in Alzheimer’s and HIV trials
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Research
Reductive power of hydrated electrons unleashed with green lasers
New technique produces solvated electrons with a visible-light responsive photocatalyst
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Review
Organic chemistry: a very short introduction
A beginner’s guide to one of the most exciting areas of modern science
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Feature
Photoredox: charge of the LED brigade
Forget fluorescent light bulbs, photochemistry has become a lot more sophisticated
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Opinion
Forcing fluorines into shape
Sometimes unnatural molecules can be more challenging to synthesise than natural metabolites
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Research
Super-electrophilic ions enable selective modification of bioactive molecules
New technique will help medicinal chemists explore chemical space
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Opinion
An opportunity ignored
Dismissing ideas that were ‘not invented here’ is like walking past a $100 bill
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Research
Interlocked molecules encircle stable radicals
Catenane radicals with up to seven oxidation states might one day be used in memory devices
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Opinion
That’s stereochemistry
Recognising the tetrahedral nature of carbon changed science as well as explaining it
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Research
Hydrogen bonded system faces strength test
New tool can measure noncovalent interaction under non-equilibrium, near-physiological conditions
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Research
An absolute acidity scale for solvents
Comprehensive solvent acidity scale could help make acid-catalysed reactions more reliable and reproducible