Organometallics – Page 2
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ResearchIridium pincer complex promotes unprecedented ether decarbonylation
Scientists stumble upon unique transformation that involves breaking an extraordinary number of bonds
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OpinionThe Nobel prize that got binned
Ferrocene is a classic example of a discovery that was dismissed as a failed experiment
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ResearchA whole new world for barium, including first ever non-ionic barium fluoride
Ligand tames barium, making precursor to first barium–tin and first molecular barium–fluorine bond
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ResearchMetal complexes outperform organics in antimicrobial analysis on crowdsourced compounds
Could this study prompt drug developers to rethink their reluctance to making metal-based pharmaceuticals?
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ResearchInorganic fragment library ready to help drug discoverers reach neglected regions of chemical space
A new approach to fragment-based drug design
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NewsDoes the periodic table make more sense upside down?
UK researchers argue an inverted table works better for students
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ResearchDesigner copper complexes offer route to cheaper organic LEDs
New material cuts out precious metals
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ResearchMolecular shapeshifting observed at ultrafast speeds
Study reveals that structural transformations occur just as fast as molecular vibrations
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ResearchAlkaline earth carbonyls break the rules
Complexes of Ca, Sr and Ba adopt a transition metal-like 18-electron configuration, rather than the octet more usually found in main group compounds
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ResearchCopper–arene complex tamed by silylene
Ligand selection unleashes first monomeric [Cu(η6-C6H6)]+ complex
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ResearchTitanium complex converts methane to alkenes at room temperature
New work illustrates the ‘crucial steps’ required for a process to make useful chemical feedstocks from methane
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Podcasttert-Butyl lithium or t-BuLi
A pyrophoric reagent that remains one of chemistry’s staples and the liquid salts that can tame its wild reactivity
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OpinionNickel catalyst couples alcohols and carbon dioxide
Flexibility and low cost make nickel a firm favourite in catalysis
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ResearchBringing ferrocene full circle
Cyclic oligomers made from iconic organometallic compound hold possibilities for electronics
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ResearchRare mixed-valent Si2H radical isolated
N-heterocyclic carbenes used to trap subvalent disilicon hydride species
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PodcastTetraethyl lead
For decades, automobile fuel had a dangerous additive: Tetraethyl lead. Matt Gunther explains why a toxic compound was added to our fuel
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ResearchQuintuple bond activates small stable molecules
Exotic complexes suggest route to synthetic feedstock
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FeatureMetallic plastic
Metal-containing polymers stand to benefit from the mechanical properties of polymers and the chemical properties of metals. Tom Westgate finds that recent advances in design and synthesis make these materials far more than mere chemical curiosities
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