All Reactions and synthesis articles – Page 16
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Research
Programmed cyclodextrin synthesis picks out specific molecule from 117,655 possibilities
Thioacetate orienting group allows for fine-tuned cyclodextrin functionalisation
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Research
Tandem catalysis and smart design offer new route to polypropylene plastic
Selective combustion of hydrogen by-product improves oxidative propane dehydrogenation yields
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Research
Neural network based on autocatalytic reaction performs image classification
Click reaction between small organic molecules used to execute a computing task
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Feature
Flow chemistry surges forward
The long-discussed technique could help make pharma manufacturing more distributed, finds Andy Extance, and create opportunities for chemists with the right skills
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Careers
A free online guide to master Schlenk lines
Andryj Borys shares his knowledge on air-sensitive chemistry through an open-access handbook and website
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Research
Double bond metathesis extended to germanium compounds
Partner swapping reaction carried out with digermene compounds, with no need for a catalyst
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Research
Electrochemistry enables new, greener route to aromatic sulfonamides
One-step, metal-free, scalable route synthesises key functional group in drug discovery
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Research
Redox switches up possibilities for signal transduction in artificial cells
Vitamin C triggers membrane translocation in a synthetic system, which generates an amplified fluorescent response
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Research
HPLC alternative purifies peptide cocktails in record time
Reductively cleavable brominated peptide linker unlocks contamination-free traceless release from solid support
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Research
Catalyst turns mixed plastic waste into natural gas
Swiss researchers are now scaling-up the technology
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Opinion
Space, energy and synthetic half-reactions
Matching driving forces with intermediates to predict new chemistry
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Research
Molecular firing range allows surprisingly specific bond breaking
At energies equivalent to temperatures of several thousand Kelvin fragmentation is unexpectedly precise
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Research
Zinc a double-edged sword when it comes to nickel catalysis
Mechanistic studies shed light on the role of zinc salts in cross-coupling reactions
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Research
Carbon dioxide turned into methanol by exploiting daily temperature changes
Pyroelectric catalysis technology used to make sustainable fuel
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Research
Segregation strategy for methane conversion enables new chemical reactivity
Model built to quantify effect of compartmentalisation on organometallic reaction
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Research
Single atom catalysts double up to link oxidation and reduction
Photosynthesis inspires dual electrolytic system where iron-supporting shell envelops palladium-supporting ‘yolk’
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Research
Amine might end palladium’s reign over classic cross coupling reaction
Suzuki reaction now comes in an organocatalysed format
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Research
Nitrogen radical chemistry sees the light
Daniele Leonori explains how his group is taking inspiration from 30-year-old chemistry to devise shorter syntheses for bioactive compounds
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Research
Catalyst offers low temperature route to produce hydrogen
Molybdenum carbide catalysts with low loadings of platinum can perform water–gas shift reaction at just above room temperature
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Research
Electric fields flick the quantum-tunnelling switch in cold reactions
Reaction kinetics affected by direction of external electric field under cryogenic conditions