All Reactions and synthesis articles – Page 17
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Research
Ultrasound tops traditional synthesis in hunt for elusive golden polymer
Mechanochemical synthesis of fluorinated polyacetylene shows that mechanical force can tackle transformations that are near impossible with solvent-based chemistry
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Hybrid resin offers new dimension in flow reactor printing
New resin enables chemical resistance, UV transparency and the potential for surface functionalisation
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New, cheaper catalyst turns carbon dioxide into jet fuel
Researchers envisage extracting carbon dioxide from the atmosphere to make ‘net-zero’ hydrocarbon fuel for jet engines
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DFT boosts machine-learning models of nucleophilic aromatic substitution reactions
Best of both worlds for computational organic chemistry predictions
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Mechanochemistry makes ammonia under mild conditions
Ball-milling process could reduce energy consumption associated with key fertiliser feedstock
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How to solve a ‘nasty’ compound’s structure with a million-Euro synchrotron
Chemists overcomes challenges of handling explosive and toxic nitrogen to investigate its structure using Germany’s most expensive x-ray source
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Katritzky reaction rate turbocharged by glassware
Amine transfer reaction can be sped up as much as 33 times by the presence of glass
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Aluminium shows unprecedented selectivity for breaking toughest bond
An aluminium complex reacts with tricyclic hydrocarbon’s most stable ring while ignoring easier-to-break carbon–carbon bonds
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Webinar
Emerging strategies in covalent inhibition
Join us for a review of emerging strategies for the development of covalent inhibitors in drug discovery
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Research
Surface chemistry discovery points way to cheaper water splitting
New experiments reveal the true mechanism of electrocatalysed oxygen evolution reaction
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New approach to make chiral amines from internal olefins revealed
Clever reaction design enables the direct addition of N–H bonds to unactivated internal alkenes with high enantioselectivity
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Webinar
Enhanced understanding of lithium ion battery chemistry through isothermal calorimetry
Join us to learn how to gain novel insights into battery materials and cell behavior through isothermal calorimetry, allowing improved performance and lifetime prediction
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Big data behind cheat sheets for optimising Buchwald–Hartwig cross-couplings
Interactive tools based on data from 62,000 reactions could help chemists eliminate human biases when selecting reaction conditions
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Machine-learning software competes with human experts to optimise organic reactions
Researchers say the tool is an inexpensive approach to yield optimisation for chemistry labs that can’t afford robots
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Machine-designed natural product syntheses pass ‘Turing test’ for chemistry
Software updates allow Chematica to design sophisticated synthetic pathways, planning each step four or five moves ahead
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Webinar
Spectra 200 S/TEM: A workhorse for catalyst characterisation
Join us to learn about advanced catalyst materials characterisation using the state-of-the-art Thermo Scientific Spectra 200 S/TEM
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Research
Elusive formyloxyl radical hints at unique, and more sustainable, chemical transformations
An electrocatalytic route for forming the formyloxyl radical in situ enables researchers to probe its unexpected chemistry
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Porphyrin assembly is ‘largest pure organic synthetic cage’ ever made
Hollow structures could find use in light harvesting or cargo-trafficking systems
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Traditional olefin hydroboration yields surprising trans-isomers
A very common organic reaction under ordinary conditions has produced significant amounts of unexpected trans-products for the first time
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Hammett equation parameters optimised for improved predictive power
Update overcomes limitations and eliminates human biases intrinsic to the original formulation