All Reactions and synthesis articles – Page 29
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Research
16 benzene rings make up bulkiest ever acene
Largest perphenylacene behaves like tetracene in an inert hydrocarbon sheath
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Research
Liquid metal turns back time on fossil fuel burning
Electrochemical reduction with liquid metal electrode converts carbon dioxide back into carbon
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Podcast
Ferrous sulfate
The iron compound that has been turning oak gall extract into indelible ink for centuries, but is now eating though our ancient manuscripts and musical scores
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Opinion
We’re going to need a bigger flask
Scaling up reactions is easy to get wrong in a variety of ways
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Research
The five reactions on every organic chemist’s wish list
Synthesis has some catching-up to do to create the reactions every drug discovery chemist dreams of
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Podcast
Nitrogenase
The mysterious enzyme that can beat the world’s biggest chemical process when it comes to breaking the dinitrogen triple bond
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Research
Solar cell tries its hand at organic synthesis
Nitrogen heterocycles can be attached to aromatic compounds in a single step using an iron oxide photocatalyst under visible light
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Research
Light-activated chirality switch directs enantiomeric excess
Photoexcitation can transform a racemic ligand into one of its enantiomers
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Research
Mechanochemical simulations surprise with crystals behaving like putty
Inaugural picture of what happens when materials are bashed together reveals unexpected level of molecular transfer
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Research
Mirrors in the dark enable chemical control
Vibrational strong coupling with electromagnetic fluctuations can tilt a molecule towards one reaction pathway or another
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Research
Remarkably durable water splitting photocatalyst lasts for half a year
Catalyst overcomes long-standing barrier to commercial sunlight-driven hydrogen generation
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Research
Taking the pressure off catalytic carbon dioxide conversion
Chemists obtain formate from carbon dioxide at atmospheric pressure without using hydrogen gas
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Research
Walking radicals relocate double bonds
Nickel-guided radicals walk along carbon chains to make E-alkenes from terminal alkenes
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Research
Forceful treatment stabilises drug antibody linkages
Ultrasonic energy could modify maleimide–thiol connections in cancer treatments in volume
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Review
Elemental: How the Periodic Table Can Now Explain (Nearly) Everything
A whistle-stop tour of the periodic table
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Podcast
Omega-3 fatty acids
Many consume cod liver oil due to 'a vague sense we should be taking them for something' – but what to the omega-3 fatty acids actually do?
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Opinion
In search of ultimate selectivity
A catalyst that reacts only with aryl iodides, spurning bromides and chlorides
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Research
Flexible route to enantiomerically enriched cyclobutanes
System for modifying square starting molecule could be gateway to numerous bioactive molecules