All Reactions and synthesis articles – Page 31
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Research
Catalyst predictor shows drug manufacturing promise
Joint industrial–academic team develops and validates force-field tool for identifying ligands for enantioselective catalysis
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Research
Weird mechanism behind catnip compound’s biosynthesis uncovered
Nepetalactone – the compound cats go crazy for – is made by a two-step procedure that is unlike any other in terpenoid biosynthesis
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Research
Crop rotation for catalysts
Chemists take a leaf out of agriculture books to devise method for extending catalyst lifetime
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Podcast
Low-background steel
Post-nuclear steel is a little bit radioactive, so for some specialist jobs we need to find a source of steel from before the bomb
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Research
Double umpolung approach to amino amide synthesis
Unusual disconnection strategy behind stereocontrolled route to β-amino amides
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Research
Erythropoietin benefits from controlled sugar-coating
Click chemistry allows glycosylation at virtually any synthetic stage
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Research
Robotic organic synthesis to make reproducibility simple in chemistry
Chemputer claims universality after making three drugs without human intervention
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Podcast
Tin chlorides
The compounds that put the 'tin' in tin cans and help you to reflect on your appearance
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Research
Computation trick cuts total synthesis from 27 to nine steps
Quantum mechanical modelling shows speedy route to terpene natural product
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Podcast
Propanethial-S-oxide: how chopping onions makes you cry
Kat Arney’s investigation of the pungent chemical in onions is enough to bring tears to your eyes
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Research
Molecular decoration determines origin of MOF acidity
Analytical combo used to pinpoint strong Brønsted acid site in promising next-generation solid acid catalyst
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Research
Phosphorus beats palladium in connecting nitrogen rings
An entirely metal-free reaction goes where no traditional cross-coupling has gone before – to link pyridines
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Research
Catalytic fix for nitrogen fixation
Single-atom ruthenium catalyst doubles efficiency of electrochemical reduction of nitrogen to ammonia
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Research
Cocrystal intermediate is first for mechanochemistry
In situ Raman spectroscopy reveals how reactants align prior to forming new bond
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Research
Hidden gene cluster unearthed to reveal antibacterial natural product
Scientists encourage soil microorganisms to express themselves
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Research
Engineered protein mimics photosynthesis to capture carbon
Genetically modified enzyme rivals heavy metal catalysts in photochemical carbon dioxide reduction
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Research
Propeller molecule acts as chirality sensor for solvents
Unusual chiral induction phenomenon observed in a molecular system
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Research
Mercury poisoning test gets it wrong for palladium catalysts
The 100-year-old mercury drop test to distinguishing between homogeneous and heterogeneous catalyst is not as reliable as chemists thought
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Research
Bond-breaking reaction chops up wood chemical
Reaction that splits biphenols in two could convert lignin into useful chemicals