All Reactions and synthesis articles – Page 39
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Research
Route to fiendishly complex marine molecule cut in half
Shortcut to promising natural product already in Alzheimer’s and HIV trials
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Research
Reductive power of hydrated electrons unleashed with green lasers
New technique produces solvated electrons with a visible-light responsive photocatalyst
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Research
All-metal ion mimics carbonate
Seven month reaction delivers peculiar tin–bismuth anion that is first solution-stable all-metal carbonate analogue
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Podcast
Phosphorus chlorides
A hugely useful group of compounds that have a distinct dual personality
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Review
Organic chemistry: a very short introduction
A beginner’s guide to one of the most exciting areas of modern science
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Research
Molecules grown into largest fractal triangle
Fifth order Sierpinski triangle assembled out of iron and organic molecules on a gold surface
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Research
Single molecular machine produces four chiral products
A programmable platform for stereodivergent synthesis
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Feature
Photoredox: charge of the LED brigade
Forget fluorescent light bulbs, photochemistry has become a lot more sophisticated
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Research
Chiral catalyst switches selectivity in seconds
Helical copper compound’s enantioselectivity can be inverted while reaction is running
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Opinion
Forcing fluorines into shape
Sometimes unnatural molecules can be more challenging to synthesise than natural metabolites
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Research
Super-electrophilic ions enable selective modification of bioactive molecules
New technique will help medicinal chemists explore chemical space
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Research
Patchy particles with predictable patterns
Controllable, predictable method produces patchy particles on a large scale
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Opinion
An opportunity ignored
Dismissing ideas that were ‘not invented here’ is like walking past a $100 bill
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Podcast
tert-Butyl lithium or t-BuLi
A pyrophoric reagent that remains one of chemistry’s staples and the liquid salts that can tame its wild reactivity
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Research
DNA synthesis is just a click away
The technique could be an efficient and cost-effective method of gene synthesis
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Research
Carbohydrates promoted in new prebiotic theory
Aldol reactions between interstellar materials can make DNA sugar
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Opinion
That’s stereochemistry
Recognising the tetrahedral nature of carbon changed science as well as explaining it
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Research
An absolute acidity scale for solvents
Comprehensive solvent acidity scale could help make acid-catalysed reactions more reliable and reproducible