All Reactions and synthesis articles – Page 46
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ResearchDesigner rhodium catalyst targets selected C–H bonds
Catalyst’s carbene pocket shows a preference for specific links without needing a directing group
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ResearchAFM study could prompt surface catalysis rethink
Intermediates predicted by theory don’t match those seen under the microscope
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ResearchGoodbye borazine, hello hydrogen
New catalyst unleashes more hydrogen for ammonia borane-powered fuel cells
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ResearchBacteria seeded with synthetic pathways
Living factories provide alternative to complicated chemical syntheses or farming hectares of crops
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ResearchActive esters enable powerful new route to carbon–carbon bonds
‘Insanely easy’ approach to form previously tricky sp3–sp3 bonds already being used by pharma just three months after discovery
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OpinionAn odd couple
Coupling unactivated phenols with amines requires an unusual approach, as Karl Collins discovers
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ResearchElusive Suzuki intermediates finally captured
Backing for model that ‘jumped straight into textbooks’ without any experimental evidence
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ResearchRibosome mimic assembles made to order molecules
DNA machine can be programmed to produce a wide range of polymers and even keeps a record of each one it makes
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OpinionChemistry under control
There’s more to influencing the science of change than temperature and catalysts
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ResearchMacrocyle aromaticity switch is all about that base
Deprotonation triggers rare conformation change in expanded porphyrin
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OpinionToxicity is a hazardous waste
We must teach students how to avoid environmental impact rather than accept itas an inherent part of chemistry, argues John Warner
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ResearchCarbon monoxide where you want it, when you want it
Hazardous bottled gas redundant thanks to methods that generate it at the point of use
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ResearchWhipping oils into a frenzy
Armour plated bubbles are the key to stable, temperature sensitive air-in-oil foams
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ResearchA new twist on aromaticity
Researchers break record for benzene ring with the largest twist angle
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ResearchHypervalent iodine reagent’s aversion to conversion
A case of mistaken identity inspires a closer look at the structural stability of Togni reagent I
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ResearchNew type of hydrogen bond discovered
First non-classical hydrogen bond involving boron–hydrogen to π-system observed
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ResearchMolecular surgery stitches up water dimer in fullerene cage
First isolation of dimer to aid fundamental studies of hydrogen bonding
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ResearchChemists get the ball rolling on titanium oxide fullerenes
Titanium oxide nanocluster has been captured under electron microscope