All Reactions and synthesis articles – Page 47
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Research
Electrostatic field powers up reaction rate
Applying electrical potential to Diels-Alder system confirms prediction of catalytic effect that defies received chemical wisdom
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Research
Nanosynthesis under flow is far less slow
‘Dial-a-particle’ strategy tunes the size and shape of nanostructures
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Research
Catalyst offers cheaper route to disinfect water
Nanoparticles can be used to produce small amounts of hydrogen peroxide with less precious metals in straightforward process
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Research
Chemists hit a top synthetic target with pyramidal compounds
Non-classical covalent pyramidanes surprise with high bonding ionicity
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Research
Boat conformer launches new carbon bond-forming reaction
Palladium catalyst exploits usually hard-to-access configuration to achieve C–H activation
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Research
New process draws poison from nitrile production
Nickel and aluminium catalysts obviate need for explosive and toxic hydrogen cyanide used to make important precursors for pharmaceuticals, cosmetics and agrochemicals
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Opinion
Dead in the water
A healthy sense of hydrophobia is a useful trait in the plant, says Chemjobber
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Research
Incredibly rare and unstable mineral shows catalytic clout
Georgeite shows promise as a catalyst precursor for the synthesis of methanol
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Research
‘Forbidden chemistry’ drives carbon bond forming sequence
Flow process harnesses unstable diazo compounds in room temperature reactions
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Research
A small molecule’s big moment
Substituted benzene has the largest dipole ever observed in a neutral molecule
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Research
Drug labelling problems ironed out by new catalyst
Cost-effective method to tritiate compounds offers way to track drug metabolism while minimising radioactive waste
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Research
Easy addition of ‘unnatural’ strained rings boon for drug chemists
Technique can slow metabolism of medicines, giving them more time to work
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Research
First nitrido–imido–amido complex made
Intriguing compound has single, double and triple Cr–N bonds from the same chromium atom
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Opinion
Scratching chiral surfaces
Heterogeneous asymmetric catalysis beyond hydrogenation is tricky, says Karl Collins
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Research
Glycerol-free strategy sweetens biodiesel synthesis
Catalytic process that turns plant oils into biofuel dodges annoying byproduct
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Research
Cutting edge chemistry in 2015
We take a look back at the year’s most interesting chemical science stories
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Opinion
Foaming at the reactor mouth
Turning a 1000 gallon reactor into a giant bubble bath is far from soothing, says Chemjobber