All Suzuki–Miyaura articles
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Research
Study questions sustainability benefits of replacing palladium with nickel in cross-coupling reactions
Common belief that Earth-abundant metals are green replacements for palladium may be misleading
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Research
Classic cross-coupling reactions rerouted to make new products
Combination of Suzuki–Miyaura and Buchwald–Hartwig couplings produces carbon–nitrogen–carbon linked compounds
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Research
First GPT-4-powered AI lab assistant independently directs key organic reactions
Large language model takes control after being prompted to do Suzuki and Sonogashira couplings
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Opinion
Embracing oddities
When new chemistry looks like alchemy or witchcraft, it’s worth taking notice
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Research
AI discovers the best general conditions yet for cross couplings, doubling yields
Algorithm works with robotic experimenter on tricky Suzuki–Miyaura reactions
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Opinion
Don’t let the burden of proof squeeze the life out of ideas
Extraordinary claims can be extraordinarily stimulating
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Research
Amine might end palladium’s reign over classic cross coupling reaction
Suzuki reaction now comes in an organocatalysed format
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Research
Carbon bond formation reproducibility runs into reagent stability problem
Solid sodium alkoxides react with carbon dioxide and can hamper performance – but sometimes improve it
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Research
Introducing the tubulararenes, a new class of strained aromatic compounds
Electroactive container molecules built from the bottom-up
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Research
Palladium catalyst voyage prompts carbon–carbon bond formation rethink
Suzuki–Miyaura cross-coupling catalyst atoms leach away but then return to their supports
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Research
Mechanochemistry bypasses need for solvents in Suzuki coupling
Adding a small amount of olefin dramatically improves challenging solid-state coupling reaction
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Research
Minty-fresh solvent for sustainable cross-couplings
Eucalyptol could replace diethyl ether, DMF, THF and toluene in many synthetic reactions
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Research
Warnings that dirty stirrer bars can act as phantom catalysts
Metal contaminants that can’t be removed by cleaning can be a serious problem for sensitive reactions
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Research
1500 reactions per day go with the flow
Automated flow chemistry system puts high-speed spin on drug discovery
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Research
Suzuki–Miyaura–hydrogenation targets 3D drugs
Researchers design a new pathway to make sp3 enriched drug molecules
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Research
Catalyst made from plant roots promotes Suzuki reaction
Ecocatalyst recycling strategy could be used to recover precious metal pollutants from contaminated sites
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Research
The Goldilocks of heterogeneous catalysis
Dangling thiols anchor palladium within MOF without poisoning its catalytic activity